superhydrofobiciteit op een spuitgegoten werkstuk

Dirt-repellent surfaces via femtosecond laser technology

02 November 2022
Article
Eddy Kunnen
Biomimetics or 'biomimicry' imitates principles found in nature to solve practical problems, such as modifying a surface to add certain properties to it. Thus, surfaces can be made water-repellent, dirt-resistant, self-cleaning, ... by giving them a microstructure. This is possible today with various precision techniques, including microtexturing with ultra-short pulsed lasers.

Dirt repellent surfaces can already be found in various applications today. Consider, for example, the water repellency of clothing, self-cleaning greenhouse glass or filters that separate oil and water. A further example are coatings on a ship's hull against algae and barnacle fouling that increase water resistance and fuel consumption. Often, such an anti-fouling property can be obtained by applying a coating, but structured surfaces also have potential. What structures should look like to prevent pollution can be learned from nature. New technologies including ultra-short pulsed lasers (abbreviated to 'USL', also known as femtolasers) allow mimicking these natural structures.

Anti-dust

The archetype example is the surface of a lotus leaf, from which water beads off. Small structures on the leaf limit interaction with the water. Surface tension then causes the water to settle into its natural droplet shape. These roll off over the surface of the leaf, taking any dust with them. At Sirris, we recreate these structures using ultra-short pulsed lasers. The structure can be applied directly to metal, or indirectly, for example via injection moulding in a mould treated via USL.

microscoop opnames vuilafstotend oppervlak
Micro- and nanostructures on a lotus leaf that cause droplets to roll off it.
superhydrofobiciteit op een spuitgegoten werkstuk
Superhydrophobicity on an injection-moulded workpiece made at Sirris

Anti-algae growth

These properties should always be seen specifically and in the right circumstances. Among other things, recent research has shown that the dirt-resistant properties of a lotus-type surface do not help against algae growth (see figure below). The superhydrophobic effect disappears after an hour of underwater exposure, so algae growth eventually occurs anyway.

A better source of inspiration to combat this fouling is found in hair: after all, you don't see barnacles growing on the skin of a shark, but you do on that of a humpback whale, for example. This is because microscopic structures such as hairs or sharp edges prevent this attachment process. A structure based on sharkskin such as Sharklet, does work here.

sharklet patroon
Sharklet pattern with antibacterial properties.
tijdelijk karakter van ondergedompeld superhydrofoob oppervlak
Temporary character of submerged superhydrophobic surface.

Anti-oil contamination

Oil contamination on water is a well-known phenomenon, but how do you solve it? How do you separate oil back from water? Filters, augmented with USL, may offer a solution. The figure below shows what happens when a water-diesel mixture is poured over a filter treated with USL. The diesel cannot pass through the membrane, while the water does. In this way, water and diesel are separated into the left and right cups, respectively.

water-dieselmengsel over filter

At Sirris in Diepenbeek, research is being done on functionalising surfaces. Using our ultra-short pulsed laser setup, surfaces are made superhydrophobic, friction-reducing or light-absorbing, among others. Do you have any questions about improving one of your surfaces, about dirt repellency or adding another a functionality? Then please contact us!

This blog post was published as part of the SURFACESCRIPT COOCK project

 

Sources:

  • https://www.sharklet.com/technology-overview/
  • The anti-biofouling properties of superhydrofobic surfaces are short-Lived, Gi Byoung Hwang et al., ACS Nano 12, p. 6050-6058 (2018)
  • Sharkskin-mimetic desalination membranes with ultralow biofouling, Wansuk Choi et al., J. Mater. Chem. A. 6, p. 23034-23045 (2018)
  • Antifouling Surfaces and Materials, from land to marine Environment, Feng Zhou, ISBN 978-3-662-45203-5.
  • Recent Advances in Femtosecond Laser-Induced Surface Structuring for Oil-Water Separation, Ali Sami Alnaser et al. , Applied Sciences 9, p. 1554 2019.

Authors

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